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الثلاثاء، 5 يناير 2016

What To Consider When Choosing The Diffusion Coatings

By Dennis Campbell


Semiconductors and PV manufacturers are faced with significant corrosion challenges. They target to produce metallic components that can withstand extreme conditions such as varying pH levels, extremely high and low temperature, high pressure, and exposure to different environmental elements that significantly affects their physical properties. More often, the solution often involves diffusion coatings to give the base metal physiochemical and structural properties making them suitable to operate under extreme physical conditions.

The top choice coating materials include the steel alloy, aluminum, alloy, chromium and titanium alloys, and silicon. Most of these are able to stand varying pH levels, extreme temperatures, and other physical conditions, offering a protective cover to iron materials, nickel, cobalt, steel and carbon among other metals.

This makes the metals reliable and long lasting thereby allowing for the manufacture of critical machine components and components for other applications. The process is used to manufacture and process gas turbine components such as cases, blades, vanes, and gate valves, pump impellers as well as power generation components.

The level of resistance offered to the base metals enables them to work effectively in conditions of temperatures as high as 2100 degrees Fahrenheit with no risk of spallation. As such, all metallic components of the machine or system that is exposed to extreme temperature, pressure, pH level and other physical conditions have to be diffusion coated.

In order to select the right corrosion resistant coating for the semiconductor, metals, or PV manufacturing applications, the factors like possible contamination must be considered. Generally, most alloys are known leach metal ions into the process stream which has an impact on the yield. Silicon on the other hands improves the corrosion resistance and prevents leaching all at the same time. It does not cause process contamination.

To begin with, compatibility ranks high in the list of considerations when selecting the right diffusion coating material. No single metal alloy or compound can offer full protection against all forms of corrosive elements. However, the operation environment is also unlikely to expose the metal to all extreme conditions, as such; the wise option involves making the selection basing on the most likely condition of the process.

The second consideration is the level of concentration. This affects the rate at which corrosion takes place. Most acids increase the rate of corrosion with an increase in concentration. By fully understanding the acid or base, its level of concentration and the fluid velocity, you will be able to make an informed choice.

The other factor is the period of exposure. A metal corrodes faster when exposed to the corrosive element for longer time period. The situation where the metal is exposed to the high temperature or acidic environment periodically, it is wetted and dried without rinsing in the process, the rate of corrosion is significantly accelerated.

When dealing with acids and bases, pH level must be given a special consideration. Low pH (acidic conditions) does not have a significant impact on silicon. Basic condition (high pH) level on the other hands is likely to dissolve silicon coat. In regards to temperature, the rate of corrosion is high when the temperature is high for aluminum and stainless steel given that the passive film that prevents corrosion is dissolved as temperature increases.




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